temephos removal from water samples by silver modified zero-valent iron nanoparticles

نویسندگان

roohollah shiralipour chemistry department, college of science, shahid chamran university, ahvaz, ir iran; chemistry department, college of science, shahid chamran university, ahvaz, ir iran. tel: +98-6133360018, fax: +98-6133337009

behrooz zargar chemistry department, college of science, shahid chamran university, ahvaz, ir iran

hooshang parham chemistry department, college of science, shahid chamran university, ahvaz, ir iran

چکیده

conclusions briefly, the current study represents a novel method to eliminate temephos as an organophosphate compound from water samples with modified zero-valent iron nanoparticles. background temephos is an organophosphate pesticide used as larvicide in the environment. although not extremely hazardous, it can be risky for human health in the moderate concentrations. objectives this study investigated the quantitative removal efficiency of temephos, an organophosphate pesticide, from contaminated water by silver-modified zvinps. in addition, the operational parameters affected on removal process were optimized. materials and methods in the current study, three water samples from different parts of iran such as ahvaz tap water, the karoon river passing through khoramshahr city, and the caspian sea were collected. a new method for effective removal of temephos from the sample solutions by silver modified zero-valent iron nanoparticles as an efficient adsorbent was introduced. results for a typical solution in which temephos was removed about 21% by iron zero-valent nanoparticles, modification by silver improved removal method was up to about 99%. the required time for the complete removal of temephos was about eight minutes. variation of ph and concentration of kno3 as an electrolyte was considerably ineffective on the efficient temephos removal. adsorption studies of the method were followed by langmuir isotherm. maximum temephos adsorption amount was 12.65 mg/g under optimal conditions. the proposed method was simple, fast and safe to treat temephos polluted waters. preparation of the adsorbent was easy and removal time was short.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Enhanced chromium (VI) removal using activated carbon modified by zero valent iron and silver bimetallic nanoparticles

Recently, adsorption process has been introduced as a favorable and effective technique for the removal of metal ions from aqueous solutions. In the present study, bimetallic nanoparticles consisting of zero valent iron and silver were loaded on the activated carbon powder for the preparation of a new adsorbent (PAC-Fe(o)/Ag). The above adsorbent was characterized by using XRD, SEM and TEM tech...

متن کامل

modified zero valent iron (zvi) nanoparticles for removal of manganese from water

manganese is one of the significant raw materials for various industries and most difficult element to remove from water because of its high solubility. the treatment of mn (ii) contained wastewater is stringent for environmental preservations. in the present study adsorption of mn2+ on zero-valent iron nanoparticles synthesized by chemical reduction process and modified with phosphate coating ...

متن کامل

effect of zero-valent iron nanoparticles on vocs removal from air with a modified zeolite bed

volatile organic compounds (vocs) are in categories of mankind and environmentally harmful materials. some of vocs are also carcinogenic and mutagen. because of expanded application of these compounds as various domestic and industrial usages, prevention of environmental contamination of these compounds is a substantial issue.  in this study, the effect of zero-valent iron nanoparticles applica...

متن کامل

High-level arsenite removal from groundwater by zero-valent iron.

The objectives of this study were to conduct batch and column studies to (i) assess the effectiveness of zero-valent iron for arsenic remediation in groundwater, (ii) determine removal mechanisms of arsenic, and (iii) evaluate implications of these processes with regard to the stability of arsenic and long-term remedial performance of the permeable reactive barrier (PRB) technology. A high conc...

متن کامل

cadmium removal from the aquatic environment by zero-valent iron nanoparticles

introduction     cadmium as one of the toxic heavy metal, because of harmful effects on health and the environment, has attracted a lot of attention. the main sources of cadmium emissions are the environment, the waste of electroplating, melting, alloyed manufacturing, pigments, plastics, batteries, extraction and refining processes. this metal easily accumulates in different machines of people...

متن کامل

In field arsenic removal from natural water by zero-valent iron assisted by solar radiation.

An in situ arsenic removal method applicable to highly contaminated water is presented. The method is based in the use of steel wool, lemon juice and solar radiation. The method was evaluated using water from the Camarones River, Atacama Desert in northern Chile, in which the arsenic concentration ranges between 1000 and 1300 microg L(-1). Response surface method analysis was used to optimize t...

متن کامل

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید


عنوان ژورنال:
jundishapur journal of health sciences

جلد ۷، شماره ۱، صفحات ۰-۰

کلمات کلیدی

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023